Life extension of metalworking fluids (MWF) through reduction of the microbial impact

The Stuttgart Competence Center for Processing Media (PM)

The Stuttgart Competence Center for Processing Media (PM) for forming and machining – metal working fluids, forming fluids, minimum quantity fluids, multifunctional oils – puts decades of experience at your service.

 

Cooperation partner: Fraunhofer IPA and Fraunhofer IGB

Kühlschmieremulsionen zum Kühlen
Use of MWF emulsions for cooling, lubrication and protection of both metal work pieces and tools.

Metalworking fluids (MWF) serve to lubricate, cool and protect metal surfaces from corrosion when being processed (Fig. 1). In the course of time the quality of MWF emulsions deteriorates which is manifested in the separation of the oil-water emulsion. This shortens their life, increases the amount of waste and purchasing costs, reduces the life of the cutting tools, and has a negative effect on manufacturing tolerances. The main reason for the deteriorating performance of the MWF is the growth of bacteria and fungi which attack and disintegrate the organic components of the emulsified cooling lubricant (mineral oil, tensides, etc.). If they contain any pathogenic germs, these may trigger respiratory illnesses, skin irritations, or even allergic reactions in staff that come into contact with them. Therefore, MWF manufacturers use toxic biocides to keep microbe activity under control.

 

Restricted use of biocides and demulsification chemicals

In the future it will no longer be possible to ensure the stability of MWF emulsions simply by adding hazardous chemicals due to increased restrictions concerning MWF contents, the implementation of the REACH directive and stricter guidelines in the field of wastewater. Furthermore, with a view to ecological and economic aspects the addition of chemicals for the breakdown of MWF emulsions is no longer appropriate. After being broken down into emulsion phases, they need to be removed and disposed of in a time-consuming second step.

 

Environmentally-friendly technologies for increased life

The aim of the research work carried out at the Fraunhofer IGB is therefore the development of efficient, cost-effective, and clean technologies to increase the life of MWFs without the addition of toxic chemicals, and to improve their quality. In addition, the aim is to design the disposal of the MWF in such a way that part of the MWF can be recycled. For this reason, IGB’s department Physical Process Technology is investigating new physical technologies such as focused ultrasound cavitation, the application of pulsed electric and electro-magnetic fields, as well as sono-chemical and wet oxidative processes.

Focused ultrasound destroys bacteria in MWF

Initial investigations show that a reduction of microbiological contaminations, exemplified by the Gram-positive test organism Sarcina lutea, is possible by means of focused ultrasound cavitation. The progress of the bacteria concentration in relation to the treatment time with focused ultrasound is demonstrated in Fig. 2. The results were regularly achieved with an energy input of less than 200 W/l with an ultrasound combination of 23 kHz and 40 kHz at a constant temperature. Figures 3a and 3b shows that the cells of Sarcina lutea in MWF are heavily damaged by applying focused ultrasound: the decomposition of the cell walls is clearly visible.

Zellkonzentration von Sarcina lutea
Fig. 2: Progress of cell concentration of Sarcina lutea in MWF in relation to duration of treatment with focused ultrasound (simultaneous input US at 23 kHz and 40 kHz with 200 W/l). Untreated cells were used as control samples.
REM-Aufnahme vitaler Zellen von Sarcina lutea in KSS bei Versuchsbeginn
Fig. 3a: REM image of vital Sarcina lutea cells.
Bild 3b: REM-Aufnahme mit Schallimpulsen geschädigte/aufgelöste Zellen von Sarcina lutea
Fig. 3b: REM image of Sarcina lutea cells, destroyed by ultrasound cavitation.
Aufspaltung von Emulsionen mittels energetischen Feldern

Demulsification of MWF by means of electric fields

In addition to a reduction of microbiological contaminations in MWF, the recycling aspect is of particular interest. The exhausted emulsions first have to be broken down into their individual phases (water, oil, additives) before they can be used further or reused. We could demonstrate that it is possible to break down emulsions without the use of chemicals by applying induced electric fields (Fig. 4).

Funding

We would like to thank the European Union (EU), the German Federal Ministry of Economics and Technology (BMWi) and the German Federation of Industrial Research Associations ”Otto von Guericke” e.V. (AiF) for funding various projects on the extension of the life of MWF.